The aim of this project is to uncover the mechanisms of the influence of the chemical composition and the role of impurities on the properties and performance of the novel TCCT® (Trivalent Chromium-Coating Technology) coatings. These chromium coatings play an essential role in the adhesion of the lamination in steel packaging. The TCCT process was developed by Tata Steel as an alternative to a Cr(VI)-based chrome plating process to comply with European REACH regulations.

The TCCT process provides a sustainable, drop-in replacement for conventional tin-free packaging steel process. It is food-safe and suitable for a wide range of packaging applications. However, the chemistry of the trivalent plating process is complex, and the effects of ageing of the production bath are not fully understood. During the layer deposition process, some of the elements become incorporated in the chrome layer, thereby influencing the layer properties.

Previous research showed that iron and sulphate have the most impact on the deposition process. These contaminants in excess could cause a diminishing performance of the deposited TCCT layers resulting in adhesion deficiencies. The mechanisms causing the inclusion of these contaminants and the ways to control the properties of the TCCT layers will be studied at the Catalysis and Surface Chemistry group at Leiden University.